Nature of the copper-nitrosyl intermediates of copper nitrite reductases during catalysis

The design and synthesis of copper complexes that can reduce nitrite to NO has attracted considerable interest. They have been guided by the structural information on the catalytic Cu centre of the widespread enzymes Cu nitrite reductases but the chemically novel side-on binding of NO observed in al...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Hough, Michael A., Conradie, Jeanet, Strange, Richard W., Antonyuk, Svetlana V., Eady, Robert R., Ghosh, Abhik, Hasnain, S. Samar
Format: Artigo
Language:Inglês
Published: The Royal Society of Chemistry 2020
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163067/
https://ncbi.nlm.nih.gov/pubmed/34094452
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04797j
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