Unexpected Roles of a Tether Harboring a Tyrosine Gatekeeper Residue in Modular Nitrite Reductase Catalysis

[Image: see text] It is generally assumed that tethering enhances rates of electron harvesting and delivery to active sites in multidomain enzymes by proximity and sampling mechanisms. Here, we explore this idea in a tethered 3-domain, trimeric copper-containing nitrite reductase. By reverse enginee...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Hedison, Tobias M., Shenoy, Rajesh T., Iorgu, Andreea I., Heyes, Derren J., Fisher, Karl, Wright, Gareth S. A., Hay, Sam, Eady, Robert R., Antonyuk, Svetlana V., Hasnain, S. Samar, Scrutton, Nigel S.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2019
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7007197/
https://ncbi.nlm.nih.gov/pubmed/32051772
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b01266
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