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Filling a Gap: The Coordinatively Saturated Group 4 Carbonyl Complexes TM(CO)(8) (TM=Zr, Hf) and Ti(CO)(7)
Homoleptic Group 4 metal carbonyl cation and neutral complexes were prepared in the gas phase and/or in solid neon matrix. Infrared spectroscopy studies reveal that both zirconium and hafnium form eight‐coordinate carbonyl neutral and cation complexes. In contrast, titanium forms only the six‐coordi...
Shranjeno v:
| izdano v: | Chemistry |
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| Main Authors: | , , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2020
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7496348/ https://ncbi.nlm.nih.gov/pubmed/32191361 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905552 |
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