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Addition of alkynes and osmium carbynes towards functionalized d(π)–p(π) conjugated systems
The metal-carbon triple bonds and carbon-carbon triple bonds are both highly unsaturated bonds. As a result, their reactions tend to afford cycloaddition intermediates or products. Herein, we report a reaction of M≡C and C≡C bonds that affords acyclic addition products. These newly discovered reacti...
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| Pubblicato in: | Nat Commun |
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| Autori principali: | , , , , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Nature Publishing Group UK
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7495419/ https://ncbi.nlm.nih.gov/pubmed/32938934 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-18498-2 |
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