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Ammonium Catalyzed Cyclitive Additions: Evidence for a Cation-π Interaction with Alkynes
The addition of carbamate nitrogen to a non-conjugated carbon-carbon triple bond is catalyzed by an ammonium salt leading to a cyclic product. Studies in homogeneous systems suggest that the ammonium agent facilitates nitrogen-carbon bond formation through a cation-π interaction with the alkyne unit...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4732893/ https://ncbi.nlm.nih.gov/pubmed/26728333 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc08641h |
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