Multiyne chains chelating osmium via three metal-carbon σ bonds

Although the formation of metal–carbon σ bonds is a fundamental principle in organometallic chemistry, the direct bonding of one organic molecule with one metal center to generate more than two metal–carbon σ bonds remains a challenge. Herein, we report an aromaticity-driven method whereby multiyne...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Zhuo, Qingde, Lin, Jianfeng, Hua, Yuhui, Zhou, Xiaoxi, Shao, Yifan, Chen, Shiyan, Chen, Zhixin, Zhu, Jun, Zhang, Hong, Xia, Haiping
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2017
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5714968/
https://ncbi.nlm.nih.gov/pubmed/29203873
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-017-02120-z
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