Constraint of a ruthenium-carbon triple bond to a five-membered ring

The incorporation of a metal-carbon triple bond into a ring system is challenging because of the linear nature of triple bonds. To date, the synthesis of these complexes has been limited to those containing third-row transition metal centers, namely, osmium and rhenium. We report the synthesis and f...

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Detalhes bibliográficos
Publicado no:Sci Adv
Main Authors: Zhuo, Qingde, Zhang, Hong, Hua, Yuhui, Kang, Huijun, Zhou, Xiaoxi, Lin, Xinlei, Chen, Zhixin, Lin, Jianfeng, Zhuo, Kaiyue, Xia, Haiping
Formato: Artigo
Idioma:Inglês
Publicado em: American Association for the Advancement of Science 2018
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6014718/
https://ncbi.nlm.nih.gov/pubmed/29942859
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/sciadv.aat0336
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