Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules

C–C bond coupling reactions illustrate the wealth of organic transformations, which are usually mediated by organotransition metal complexes. Here, we show that a borafluorene with a B–Cl moiety can mediate sequential alkyne insertion (1,2-carboboration) and deborylation/Csp(2)–Csp(2) coupling react...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Shoji, Yoshiaki, Tanaka, Naoki, Muranaka, Sho, Shigeno, Naoki, Sugiyama, Haruka, Takenouchi, Kumiko, Hajjaj, Fatin, Fukushima, Takanori
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2016
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5025816/
https://ncbi.nlm.nih.gov/pubmed/27581519
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms12704
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