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Pd-Senphos Catalyzed trans-Selective Cyanoboration of 1,3-Enynes
The first trans-selective cyanoboration reaction of an alkyne, specifically a 1,3-enyne, is described. The reported palladium-catalyzed cyanoboration of 1,3-enynes is site-, regio-, and diastereoselective, and is uniquely enabled by the 1,4-azaborine-based Senphos ligand structure. Tetra-substituted...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7491284/ https://ncbi.nlm.nih.gov/pubmed/32511855 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202005882 |
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