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Tailored Palladium Catalysts for Selective Synthesis of Conjugated Enynes by Monocarbonylation of 1,3‐Diynes

For the first time, the monoalkoxycarbonylation of easily available 1,3‐diynes to give synthetically useful conjugated enynes has been realized. Key to success was the design and utilization of the new ligand 2,2′‐bis(tert‐butyl(pyridin‐2‐yl)phosphanyl)‐1,1′‐binaphthalene (Neolephos), which permits...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Liu, Jiawang, Yang, Ji, Schneider, Carolin, Franke, Robert, Jackstell, Ralf, Beller, Matthias
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317973/
https://ncbi.nlm.nih.gov/pubmed/32052900
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201915386
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