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Tailored Palladium Catalysts for Selective Synthesis of Conjugated Enynes by Monocarbonylation of 1,3‐Diynes

For the first time, the monoalkoxycarbonylation of easily available 1,3‐diynes to give synthetically useful conjugated enynes has been realized. Key to success was the design and utilization of the new ligand 2,2′‐bis(tert‐butyl(pyridin‐2‐yl)phosphanyl)‐1,1′‐binaphthalene (Neolephos), which permits...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Liu, Jiawang, Yang, Ji, Schneider, Carolin, Franke, Robert, Jackstell, Ralf, Beller, Matthias
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2020
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317973/
https://ncbi.nlm.nih.gov/pubmed/32052900
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201915386
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