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Site-Selective and Stereoselective trans-Hydroboration of 1,3-Enynes Catalyzed by 1,4-Azaborine-Based Phosphine–Pd Complex

A concise synthesis of monobenzofused 1,4-azaborine phosphine ligands (Senphos) is described. These Senphos ligands uniquely support Pd-catalyzed trans-selective hydroboration of terminal and internal 1,3-enynes to furnish corresponding dienylboronates in high efficiency and diastereoselectivity. X-...

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Détails bibliographiques
Publié dans:J Am Chem Soc
Auteurs principaux: Xu, Senmiao, Zhang, Yuanzhe, Li, Bo, Liu, Shih-Yuan
Format: Artigo
Langue:Inglês
Publié: 2016
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5591746/
https://ncbi.nlm.nih.gov/pubmed/27802037
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09759
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