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Regio- and Enantioselective Synthesis of Trifluoromethyl-Substituted Homoallylic α-Tertiary NH(2)-Amines by Reactions Facilitated by a Threonine-Based Boron-Containing Catalyst
A method for catalytic regio- and enantioselective synthesis of trifluoromethyl-substituted and aryl-, heteroaryl-, alkenyl-, and alkynyl-substituted homoallylic α-tertiary NH(2)-amines is introduced. Easy- to-synthesize and robust N-silyl ketimines are converted to NH-ketimines in situ, which then...
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| Vydáno v: | Angew Chem Int Ed Engl |
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| Hlavní autoři: | , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2020
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7454190/ https://ncbi.nlm.nih.gov/pubmed/32219997 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001184 |
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