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Versatile Homoallylic Boronates by Chemo-, S(N)2’-, Diastereo- and Enantioselective Catalytic Sequence of Cu–H Addition to Vinyl–B(pin)/Allylic Substitution
A highly chemo-, diastereo- and enantioselective catalytic method that efficiently combines a silyl hydride, vinyl–B(pin) (pin = pinacolato) and (E)-1,2-disubstituted allylic phosphates is introduced. Reactions, best promoted by a Cu-based complex with a chiral sulfonate-containing N-heterocyclic ca...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5267969/ https://ncbi.nlm.nih.gov/pubmed/27996213 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611444 |
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