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Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl–B(pin) Compounds to Ketones and α-Ketoesters
Broadly applicable methods for efficient and catalytic additions of easy-to-handle allyl–B(pin) (pin = pinacolato) compounds to ketones and acyclic α-ketoesters have been developed. Accordingly, a large array of tertiary alcohols can be obtained in up to >98% yield and 99:1 enantiomeric ratio. At...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Principais autores: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4978177/ https://ncbi.nlm.nih.gov/pubmed/27273249 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201603894 |
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