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Catalytic enantioselective addition of organoboron reagents to fluoroketones controlled by electrostatic interactions

Organofluorine compounds are central to modern chemistry, and broadly applicable transformations that generate them efficiently and enantioselectively are in much demand. Here we introduce efficient catalytic methods for additions of allyl and allenyl organoboron reagents to fluorine-substituted ket...

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Detalhes bibliográficos
Publicado no:Nat Chem
Main Authors: Lee, KyungA, Silverio, Daniel L., Torker, Sebastian, Robbins, Daniel W., Haeffner, Fredrik, van der Mei, Farid W., Hoveyda, Amir H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4957664/
https://ncbi.nlm.nih.gov/pubmed/27442282
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.2523
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