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Catalytic Enantioselective Epoxidation of Tertiary Allylic- and Homoallylic Alcohols

An efficient and versatile method for the enantioselective epoxidation of both tertiary allylic- and homoallylic alcohols catalyzed by Hf(IV)-bishydroxamic acid (BHA) complexes is described. Asymmetric epoxidation, kinetic resolution, and desymmetrization have been developed demonstrating the flexib...

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Detalhes bibliográficos
Main Authors: Olivares-Romero, José Luis, Li, Zhi, Yamamoto, Hisashi
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3625140/
https://ncbi.nlm.nih.gov/pubmed/23406082
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja401182a
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