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Delayed catalyst function enables direct enantioselective conversion of nitriles to NH(2)-amines
Accessing enantiomerically enriched amines often demands oxidation-state adjustments, protection/deprotection processes, and purification procedures that increase cost and waste, and limit applicability. When diastereomers can be formed, one isomer is attainable. Here, we show that nitriles, largely...
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| Publicado no: | Science |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6921520/ https://ncbi.nlm.nih.gov/pubmed/30948544 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaw4029 |
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