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Reversible Formation of Alkyl Radicals at [Fe(4)S(4)] Clusters and Its Implications for Selectivity in Radical SAM Enzymes
All kingdoms of life use the transient 5′-deoxyadenosyl radical (5′-dAdo•) to initiate a wide range of difficult chemical reactions. Because of its high reactivity, the 5′-dAdo• must be generated in a controlled manner to abstract a specific H atom and avoid unproductive reactions. In radical S-aden...
Enregistré dans:
| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2020
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7447116/ https://ncbi.nlm.nih.gov/pubmed/32696642 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c05590 |
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