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The Radical SAM Enzyme HydG Requires Cysteine and a Dangler Iron for Generating an Organometallic Precursor to the [FeFe]-Hydrogenase H-Cluster
Three maturase enzymes—HydE, HydF, and HydG—synthesize and insert the organometallic component of the [FeFe]-hydrogenase active site (the H-cluster). HydG generates the first organometallic intermediates in this process, ultimately producing an [Fe(CO)(2)(CN)] complex. A limitation in understanding...
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| Published in: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2016
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4772725/ https://ncbi.nlm.nih.gov/pubmed/26764535 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b12512 |
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