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Enantioselective Alkylation of 2-Alkylpyridines Controlled by Organolithium Aggregation
Direct enantioselective α-alkylation of 2-alkylpyridines provides access to chiral pyridines via an operationally simple protocol that obviates the need for prefunctionalization or preactivation of the substrate. The alkylation is accomplished using chiral lithium amides as noncovalent stereodirecti...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7412967/ https://ncbi.nlm.nih.gov/pubmed/31460756 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b08659 |
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