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Highly Enantioselective Direct Alkylation of Arylacetic Acids with Chiral Lithium Amides as Traceless Auxiliaries

A direct, highly enantioselective alkylation of arylacetic acids via enediolates using a readily available chiral lithium amide as a stereodirecting reagent has been developed. This approach circumvents the traditional attachment and removal of chiral auxiliaries used currently for this type of tran...

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Detalles Bibliográficos
Main Authors: Stivala, Craig E., Zakarian, Armen
Formato: Artigo
Idioma:Inglês
Publicado: 2011
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3373785/
https://ncbi.nlm.nih.gov/pubmed/21744818
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja205107x
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