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Traceless Chiral Auxiliaries for the Allene Ether Nazarov Cyclization

[Image: see text] The key stereochemical factors that determine transfer of asymmetry from the chiral auxiliary to the cyclopentenone in the allene ether version of the Nazarov reaction have been elucidated. On the basis of the new insights into the mechanism two highly effective chiral auxiliaries...

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Autors principals: Banaag, April R., Tius, Marcus A.
Format: Artigo
Idioma:Inglês
Publicat: 2008
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2674073/
https://ncbi.nlm.nih.gov/pubmed/18808186
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo801503c
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