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Traceless Chiral Auxiliaries for the Allene Ether Nazarov Cyclization

[Image: see text] The key stereochemical factors that determine transfer of asymmetry from the chiral auxiliary to the cyclopentenone in the allene ether version of the Nazarov reaction have been elucidated. On the basis of the new insights into the mechanism two highly effective chiral auxiliaries...

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Detalhes bibliográficos
Main Authors: Banaag, April R., Tius, Marcus A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2674073/
https://ncbi.nlm.nih.gov/pubmed/18808186
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo801503c
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