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Independent Generation and Time-Resolved Detection of 2’-Deoxyguanosin-N2-yl Radical
Guanine radicals are important reactive intermediates in DNA damage. Hydroxyl radical (HO•) has long been believed to react with 2’-deoxyguanosine (dG) generating 2’-deoxyguanosin-N1-yl radical (dG(N1-H)•) via addition to the nucleobase π-system and subsequent dehydration. This basic tenet was chall...
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| Publié dans: | Angew Chem Int Ed Engl |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2020
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7395871/ https://ncbi.nlm.nih.gov/pubmed/32365264 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202005300 |
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