Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid

Reactions of SiCl(4) with R(2)PO(OH) (R=Me, Cl) yield compounds with six‐fold coordinated silicon atoms. Whereas R=Me afforded the hexacoordinated tetra‐cationic silicon complex [Si(Me(2)PO(OH))(6)](4+) with chloride counter‐ions, R=Cl caused release of HCl with formation of a cyclic dimeric silicon...

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Bibliografiske detaljer
Udgivet i:Chemistry
Main Authors: Kowalke, Janine, Wagler, Jörg, Viehweger, Christine, Brendler, Erica, Kroke, Edwin
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7383495/
https://ncbi.nlm.nih.gov/pubmed/32511798
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000435
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