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Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid
Reactions of SiCl(4) with R(2)PO(OH) (R=Me, Cl) yield compounds with six‐fold coordinated silicon atoms. Whereas R=Me afforded the hexacoordinated tetra‐cationic silicon complex [Si(Me(2)PO(OH))(6)](4+) with chloride counter‐ions, R=Cl caused release of HCl with formation of a cyclic dimeric silicon...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Chemistry |
|---|---|
| Prif Awduron: | , , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
John Wiley and Sons Inc.
2020
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7383495/ https://ncbi.nlm.nih.gov/pubmed/32511798 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000435 |
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