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A requirement for an active proton delivery network supports a compound I-mediated C–C bond cleavage in CYP51 catalysis
CYP51 enzymes (sterol 14α-demethylases) are cytochromes P450 that catalyze multistep reactions. The CYP51 reaction occurs in all biological kingdoms and is essential in sterol biosynthesis. It removes the 14α-methyl group from cyclized sterol precursors by first forming an alcohol, then an aldehyde,...
Uloženo v:
| Vydáno v: | J Biol Chem |
|---|---|
| Hlavní autoři: | , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
American Society for Biochemistry and Molecular Biology
2020
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7380200/ https://ncbi.nlm.nih.gov/pubmed/32493730 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.RA120.014064 |
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