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NHC-catalyzed enantioselective synthesis of β-trifluoromethyl-β-hydroxyamides
The N-heterocyclic carbene (NHC)-catalyzed formal [2 + 2] cycloaddition between α-aroyloxyaldehydes and trifluoroacetophenones, followed by ring opening with an amine or a reducing agent is described. The resulting β-trifluoromethyl-β-hydroxyamide and alcohol products are produced with reasonable di...
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| Publicado en: | Beilstein J Org Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Beilstein-Institut
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7356285/ https://ncbi.nlm.nih.gov/pubmed/32704323 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.129 |
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