Divergent Strain‐Release Amino‐Functionalization of [1.1.1]Propellane with Electrophilic Nitrogen‐Radicals

Herein we report the development of a photocatalytic strategy for the divergent preparation of functionalized bicyclo[1.1.1]pentylamines. This approach exploits, for the first time, the ability of nitrogen‐radicals to undergo strain‐release reaction with [1.1.1]propellane. This reactivity is facilit...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Kim, Ji Hye, Ruffoni, Alessandro, Al‐Faiyz, Yasair S. S., Sheikh, Nadeem S., Leonori, Daniele
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
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Research Articles
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7318212/
https://ncbi.nlm.nih.gov/pubmed/32003916
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202000140
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