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Mechanistic Insights into the Regio‐ and Stereoselectivities of Testosterone and Dihydrotestosterone Hydroxylation Catalyzed by CYP3A4 and CYP19A1

The hydroxylation of nonreactive C−H bonds can be easily catalyzed by a variety of metalloenzymes, especially cytochrome P450s (P450s). The mechanism of P450 mediated hydroxylation has been intensively studied, both experimentally and theoretically. However, understanding the regio‐ and stereoselect...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Li, Junhao, Tang, Yun, Li, Weihua, Tu, Yaoquan
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7318132/
https://ncbi.nlm.nih.gov/pubmed/32049373
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905272
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