Desymmetrization of Dicationic Diboranes by Isomerization Catalyzed by a Nucleophile

Cationic monoboranes exhibit a rich chemistry. By constrast, only a few cationic diboranes are known, that all are symmetrically substituted. In this work, the first unsymmetrically substituted dicationic diboranes, featuring sp(2)–sp(2)‐hybridized boron atoms, are reported. The compounds are formed...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Schön, Florian, Greb, Lutz, Kaifer, Elisabeth, Himmel, Hans‐Jörg
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2020
Ämnen:
Research Articles
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317786/
https://ncbi.nlm.nih.gov/pubmed/32181953
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001640
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