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Desymmetrization of Dicationic Diboranes by Isomerization Catalyzed by a Nucleophile

Cationic monoboranes exhibit a rich chemistry. By constrast, only a few cationic diboranes are known, that all are symmetrically substituted. In this work, the first unsymmetrically substituted dicationic diboranes, featuring sp(2)–sp(2)‐hybridized boron atoms, are reported. The compounds are formed...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Schön, Florian, Greb, Lutz, Kaifer, Elisabeth, Himmel, Hans‐Jörg
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2020
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317786/
https://ncbi.nlm.nih.gov/pubmed/32181953
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001640
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