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Stimulation of Redox‐Induced Electron Transfer by Interligand Hydrogen Bonding in a Cobalt Complex with Redox‐Active Guanidine Ligand
Octahedrally coordinated cobalt(II) complexes with a redox‐active bisguanidine ligand and acac co‐ligands were synthesized and their redox chemistry analysed in detail. The N−H functions in a bisguanidine ligand with partially alkylated guanidino groups form N−H⋅⋅⋅O hydrogen bonds with the acac co‐l...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2021
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8252010/ https://ncbi.nlm.nih.gov/pubmed/33616266 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202101423 |
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