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Stimulation of Redox‐Induced Electron Transfer by Interligand Hydrogen Bonding in a Cobalt Complex with Redox‐Active Guanidine Ligand

Octahedrally coordinated cobalt(II) complexes with a redox‐active bisguanidine ligand and acac co‐ligands were synthesized and their redox chemistry analysed in detail. The N−H functions in a bisguanidine ligand with partially alkylated guanidino groups form N−H⋅⋅⋅O hydrogen bonds with the acac co‐l...

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Veröffentlicht in:Angew Chem Int Ed Engl
Hauptverfasser: Lohmeyer, Lukas, Schön, Florian, Kaifer, Elisabeth, Himmel, Hans‐Jörg
Format: Artigo
Sprache:Inglês
Veröffentlicht: John Wiley and Sons Inc. 2021
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8252010/
https://ncbi.nlm.nih.gov/pubmed/33616266
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202101423
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