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Use of Crown Ether Functions as Secondary Coordination Spheres for the Manipulation of Ligand–Metal Intramolecular Electron Transfer in Copper–Guanidine Complexes

Intramolecular electron transfer (IET) between a redox‐active organic ligand and a metal in a complex is of fundamental interest and used in a variety of applications. In this work it is demonstrated that secondary coordination sphere motifs can be applied to trigger a radical change in the electron...

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Publicado en:Chemistry
Autores principales: Haaf, Sebastian, Kaifer, Elisabeth, Wadepohl, Hubert, Himmel, Hans‐Jörg
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2020
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839521/
https://ncbi.nlm.nih.gov/pubmed/32833269
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003469
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