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Electron‐Rich, Lewis Acidic Diborane Meets N‐Heterocyclic Aromatics: Formation and Electron Transfer in Cyclophane Boranes

Herein reported are the reactions of an electron‐rich, Lewis acidic diborane with N‐heterocyclic aromatics to give first members of an unprecedented family of highly charged cationic cyclophanes with diboranyl units. Tetracationic cyclophanes with 4,4‘‐bipyridine/ 1,2‐bis(4‐pyridyl)ethylene and dibo...

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Détails bibliographiques
Publié dans:Chemistry
Auteurs principaux: Widera, Anna, Filbeck, Erik, Wadepohl, Hubert, Kaifer, Elisabeth, Himmel, Hans‐Jörg
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7155121/
https://ncbi.nlm.nih.gov/pubmed/31943435
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000189
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