Electron‐Rich, Lewis Acidic Diborane Meets N‐Heterocyclic Aromatics: Formation and Electron Transfer in Cyclophane Boranes

Herein reported are the reactions of an electron‐rich, Lewis acidic diborane with N‐heterocyclic aromatics to give first members of an unprecedented family of highly charged cationic cyclophanes with diboranyl units. Tetracationic cyclophanes with 4,4‘‐bipyridine/ 1,2‐bis(4‐pyridyl)ethylene and dibo...

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Publicado en:Chemistry
Main Authors: Widera, Anna, Filbeck, Erik, Wadepohl, Hubert, Kaifer, Elisabeth, Himmel, Hans‐Jörg
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7155121/
https://ncbi.nlm.nih.gov/pubmed/31943435
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000189
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