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Electron‐Rich, Lewis Acidic Diborane Meets N‐Heterocyclic Aromatics: Formation and Electron Transfer in Cyclophane Boranes

Herein reported are the reactions of an electron‐rich, Lewis acidic diborane with N‐heterocyclic aromatics to give first members of an unprecedented family of highly charged cationic cyclophanes with diboranyl units. Tetracationic cyclophanes with 4,4‘‐bipyridine/ 1,2‐bis(4‐pyridyl)ethylene and dibo...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Widera, Anna, Filbeck, Erik, Wadepohl, Hubert, Kaifer, Elisabeth, Himmel, Hans‐Jörg
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7155121/
https://ncbi.nlm.nih.gov/pubmed/31943435
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000189
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