Activation of Dioxygen by a Mononuclear Nonheme Iron Complex: Sequential Peroxo, Oxo, and Hydroxo Intermediates

The activation of dioxygen by Fe(II)(Me(3)TACN)(S(2)SiMe(2)) (1) is reported. Reaction of 1 with O(2) at −135 °C in 2-MeTHF generates a thiolate-ligated (peroxo)diiron complex Fe(III)(2)(O(2))(Me(3)TACN)(2)(S(2)SiMe(2))(2) (2) that was characterized by UV–vis (λ(max) = 300, 390, 530, 723 nm), Mössba...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:J Am Chem Soc
Prif Awduron: Gordon, Jesse B., Vilbert, Avery C., DiMucci, Ida M., MacMillan, Samantha N., Lancaster, Kyle M., Moänne-Loccoz, Pierre, Goldberg, David P.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2019
Pynciau:
Article
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317638/
https://ncbi.nlm.nih.gov/pubmed/31647656
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b05274
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