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A Mononuclear, Nonheme Fe(II)-Piloty’s Acid (PhSO(2)NHOH) Adduct: An Intermediate in the Production of {FeNO}(7/8) Complexes from Piloty’s Acid
Reaction of the mononuclear nonheme complex [Fe(II)(CH(3)CN)(N3PyS)]BF(4) (1) with an HNO donor, Piloty’s acid (PhSO(2)NHOH, P.A.), at low temperature affords a high-spin (S = 2) Fe(II)-P.A. intermediate (2), characterized by (57)Fe Mössbauer and Fe K- edge X-ray absorption (XAS) spectroscopies, wit...
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| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6576269/ https://ncbi.nlm.nih.gov/pubmed/30994347 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b01700 |
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