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Proton-Electron Transfer to the Active Site Is Essential for the Reaction Mechanism of Soluble Δ(9)-Desaturase
Full understanding of the catalytic action of non-heme iron (NHFe) and non-heme diiron (NHFe(2)) enzymes is still beyond the grasp of contemporary computational and experimental techniques. Many of these enzymes exhibit fascinating chemo-, regio- and stereoselectivity, in spite of employing highly r...
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| Опубликовано в: : | J Am Chem Soc |
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| Главные авторы: | , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2020
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7316153/ https://ncbi.nlm.nih.gov/pubmed/32406236 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c01786 |
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