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Communication: Charge transfer dominates over proton transfer in the reaction of nitric acid with gas-phase hydrated electrons

The reaction of HNO(3) with hydrated electrons (H(2)O)(n) (−) (n = 35–65) in the gas phase was studied using Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry and ab initio molecular dynamics simulations. Kinetic analysis of the experimental data shows that OH(−)(H(2)O)(m) is form...

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Detalhes bibliográficos
Publicado no:J Chem Phys
Main Authors: Lengyel, Jozef, Med, Jakub, Slavíček, Petr, Beyer, Martin K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7116334/
https://ncbi.nlm.nih.gov/pubmed/28915744
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4999392
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