Mechanistic Understanding of the Heterogeneous, Rhodium-Cyclic (Alkyl)(Amino)Carbene-Catalyzed (Fluoro-)Arene Hydrogenation

[Image: see text] Recently, chemoselective methods for the hydrogenation of fluorinated, silylated, and borylated arenes have been developed providing direct access to previously unattainable, valuable products. Herein, a comprehensive study on the employed rhodium-cyclic (alkyl)(amino)carbene (CAAC...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Moock, Daniel, Wiesenfeldt, Mario P., Freitag, Matthias, Muratsugu, Satoshi, Ikemoto, Satoru, Knitsch, Robert, Schneidewind, Jacob, Baumann, Wolfgang, Schäfer, Andreas H., Timmer, Alexander, Tada, Mizuki, Hansen, Michael Ryan, Glorius, Frank
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7295364/
https://ncbi.nlm.nih.gov/pubmed/32551183
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.0c01074
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