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Roles of Lewis Acid Catalysts in Diels‐Alder Reactions between Cyclopentadiene and Methyl Acrylate
The Diels‐Alder reaction of cyclopentadiene with methyl acrylate catalyzed by AlCl(3) has been theoretically investigated. M06‐2X level DFT calculations have shown that the formation of two C−C bonds is asynchronous in the cycloaddition both in the endo path and in the exo path, thus making a good c...
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| Publicado en: | ChemistryOpen |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7269005/ https://ncbi.nlm.nih.gov/pubmed/32685341 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.202000112 |
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