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Roles of Lewis Acid Catalysts in Diels‐Alder Reactions between Cyclopentadiene and Methyl Acrylate

The Diels‐Alder reaction of cyclopentadiene with methyl acrylate catalyzed by AlCl(3) has been theoretically investigated. M06‐2X level DFT calculations have shown that the formation of two C−C bonds is asynchronous in the cycloaddition both in the endo path and in the exo path, thus making a good c...

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Vydáno v:ChemistryOpen
Hlavní autoři: Sakata, Ken, Fujimoto, Hiroshi
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2020
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7269005/
https://ncbi.nlm.nih.gov/pubmed/32685341
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.202000112
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