Strong and Confined Acids Control Five Stereogenic Centers in Catalytic Asymmetric Diels–Alder Reactions of Cyclohexadienones with Cyclopentadiene

We describe a highly enantioselective Diels–Alder reaction of cross‐conjugated cyclohexadienones with cyclopentadiene, in which five stereocenters are effectively controlled by a strongly acidic and confined imidodiphosphorimidate catalyst. Our approach provides tricyclic products in excellent stere...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Ghosh, Santanu, Das, Sayantani, De, Chandra Kanta, Yepes, Diana, Neese, Frank, Bistoni, Giovanni, Leutzsch, Markus, List, Benjamin
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7383742/
https://ncbi.nlm.nih.gov/pubmed/32159921
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202000307
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