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Strong and Confined Acids Enable a Catalytic Asymmetric Nazarov Cyclization of Simple Divinyl Ketones

[Image: see text] We report a catalytic asymmetric Nazarov cyclization of simple, acylic, alkyl-substituted divinyl ketones using our recently disclosed strong and confined imidodiphosphorimidate Brønsted acids. The corresponding monocyclic cyclopentenones are formed in good yields and excellent reg...

詳細記述

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書誌詳細
出版年:J Am Chem Soc
主要な著者: Ouyang, Jie, Kennemur, Jennifer L., De, Chandra Kanta, Farès, Christophe, List, Benjamin
フォーマット: Artigo
言語:Inglês
出版事項: American Chemical Society 2019
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6541325/
https://ncbi.nlm.nih.gov/pubmed/30768254
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b13899
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