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Copper-mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride

A method for the nucleophilic fluorination of heptamethyl aryl trisiloxanes to form fluoroarenes is reported. The reaction proceeds in the presence of Cu(OTf)(2) and KHF(2) as the fluoride source under mild conditions for a broad range of heptamethyltrisiloxyarenes with high functional group toleran...

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書目詳細資料
發表在:Chemistry
Main Authors: Dorel, Ruth, Boehm, Philip, Schwinger, Daniel P., Hartwig, John F.
格式: Artigo
語言:Inglês
出版: 2020
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7266656/
https://ncbi.nlm.nih.gov/pubmed/31872488
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905040
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