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Copper-mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride

A method for the nucleophilic fluorination of heptamethyl aryl trisiloxanes to form fluoroarenes is reported. The reaction proceeds in the presence of Cu(OTf)(2) and KHF(2) as the fluoride source under mild conditions for a broad range of heptamethyltrisiloxyarenes with high functional group toleran...

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Bibliografske podrobnosti
izdano v:Chemistry
Main Authors: Dorel, Ruth, Boehm, Philip, Schwinger, Daniel P., Hartwig, John F.
Format: Artigo
Jezik:Inglês
Izdano: 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7266656/
https://ncbi.nlm.nih.gov/pubmed/31872488
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905040
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