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Copper-Mediated C–N Coupling of Arylsilanes with Nitrogen Nucleophiles

A method for the oxidative coupling of arylsilanes with nitrogen nucleophiles is reported. This method occurs with a broad range of heptamethyltrisiloxylarenes and nitrogen nucleophiles, proceeds with the arylsilane as limiting reagent, and does not require a fluoride activator with electron-poor ar...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Morstein, Johannes, Kalkman, Eric D., Cheng, Chen, Hartwig, John F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5809131/
https://ncbi.nlm.nih.gov/pubmed/27689746
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b02543
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