Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions

Controlling the chemical glycosylation reaction remains the major challenge in the synthesis of oligosaccharides. Though 1,2-trans glycosidic linkages can be installed using neighboring group participation, the construction of 1,2-cis linkages is difficult and has no general solution. Long-range par...

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Publicado no:Nat Commun
Main Authors: Hansen, Thomas, Elferink, Hidde, van Hengst, Jacob M. A., Houthuijs, Kas J., Remmerswaal, Wouter A., Kromm, Alexandra, Berden, Giel, van der Vorm, Stefan, Rijs, Anouk M., Overkleeft, Hermen S., Filippov, Dmitri V., Rutjes, Floris P. J. T., van der Marel, Gijsbert A., Martens, Jonathan, Oomens, Jos, Codée, Jeroen D. C., Boltje, Thomas J.
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2020
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7260182/
https://ncbi.nlm.nih.gov/pubmed/32471982
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-16362-x
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