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Reagent Controlled Glycosylations for the Assembly of Well-Defined Pel Oligosaccharides

[Image: see text] A new additive, methyl(phenyl)formamide (MPF), is introduced for the glycosylation of 2-azido-2-deoxyglucose building blocks. A linear α-(1,4)-glucosamine tetrasaccharide was assembled to prove the utility of MPF. Next, a hexasaccharide fragment of the Pseudomonas aeruginosa exopol...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Wang, Liming, Zhang, Yongzhen, Overkleeft, Herman S., van der Marel, Gijsbert A., Codée, Jeroen D. C.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7754192/
https://ncbi.nlm.nih.gov/pubmed/32375481
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c00703
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