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Geometric and Electronic Structural Contributions to Fe/O(2) Reactivity
While two classes of non-heme iron enzymes use ferric centers to activate singlet organic substrates for the spin forbidden reaction with (3)O(2), most classes use high spin ferrous sites to activate dioxygen. These Fe(II) active sites do not exhibit intense absorption bands and have an integer spin...
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| Publicado no: | Bull Jpn Soc Coord Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7209778/ https://ncbi.nlm.nih.gov/pubmed/32391114 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.4019/bjscc.73.3 |
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