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Enantioselective Allenoate-Claisen Rearrangement Using Chiral Phosphate Catalysts
Herein we report the first highly enantioselective allenoate-Claisen rearrangement using doubly axially chiral phosphate sodium salts as catalysts. This synthetic method provides access to β-amino acid derivatives with vicinal stereocenters in up to 95% ee. We also investigated the mechanism of enan...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7204274/ https://ncbi.nlm.nih.gov/pubmed/32182422 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c01637 |
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